- Salvage Yards, Junk Yards & Wrecker Service, Barbourville
- Sandwich Shop Restaurants, Barbourville
- Satellite & Cable TV Equipment & Systems, Barbourville
- Sawmill & Planing Mills, Barbourville
- Sawmill Supplies & Equipment Repair, Barbourville
- School - Christian, Barbourville
- Secondary Schools, Barbourville
- Security Brokers & Dealers, Barbourville
- Security Guard & Patrol Service, Barbourville - Bodyguard, Guard Dogs, Etc
- Security Services, Barbourville
- Senior Citizens Service & Health Organizations, Barbourville
- Septic Tank Site Evaluation & Design Consultants, Barbourville
- Septic Tanks & Septic Systems Contractors, Barbourville - Installation, Repair, Service, Cleaning & Pumping Septic Tanks
- Septic Tanks & Systems, Barbourville - Wholesale, Dealers & Suppliers
- Sheriff's Department, Barbourville
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- Shoe Stores, Barbourville - Mens, Womens & Kids Shoes
- Shopping & Shopping Services, Barbourville
- Social Security And Disability Attorneys & Lawyers, Barbourville
- Social Security And Disability Lawyers & Attorneys, Barbourville
- Social Services & Welfare, Barbourville
- Special Interest Schools Or Instruction, Barbourville
- Specialty Stores, Barbourville
- Sporting Goods Stores, Barbourville
- State Government, Barbourville
- Stocks & Bond Brokers, Barbourville
- Stone, Barbourville
- Stone & Rock Quarry, Barbourville - Gravel Pit, Shale, Granite, Limestone, Crushed Rock, etc
- Substance Abuse Clinics, Barbourville - Alcoholism, Addiction & Drug Abuse Treatment Centers
- Surveyor Services, Barbourville - Surveying Service
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