- Salvation Army, Madisonville
- Sand Gravel & Aggregate, Madisonville
- Sandwich Shop Restaurants, Madisonville
- Satellite Dish Antennas & Equipment Dealers, Madisonville
- Savings & Loan Associations, Madisonville
- Savings Banks, Madisonville
- Sawmill & Planing Mills, Madisonville
- Sawmill Supplies & Equipment Repair, Madisonville
- Sawmill, Paper & Woodworking Supplies, Machinery & Equipment, Madisonville
- Scrap & Waste Materials, Madisonville
- Screen Printing, Madisonville
- Secondary Schools, Madisonville
- Security & Surveillance System & Equipment, Madisonville
- Security Alarm Systems - Home & Business, Madisonville
- Security Brokers & Dealers, Madisonville
- Security Control Systems & Monitoring, Madisonville - Polygraph, Lie Detector, CCTV, Fire Sensor Equipment, Etc
- Security Guard & Patrol Service, Madisonville - Bodyguard, Guard Dogs, Etc
- Security Investigative Services, Madisonville
- Security Services, Madisonville
- Senior Citizens Centers & Meals, Madisonville
- Senior Citizens Information & Services, Madisonville
- Senior Citizens Service & Health Organizations, Madisonville
- Septic Tank Pumping & Cleaning, Madisonville - Septic Systems
- Septic Tanks & Systems, Madisonville - Wholesale, Dealers & Suppliers
- Service Industry Manufacturers Machinery, Madisonville
- Sewing Machine Repair & Service, Madisonville
- Sheet Metal Contractors, Madisonville - Sheet Metal Fabrication
- Sheet Metal Fabricators & Ductwork Contractors, Madisonville
- Sheriff's Department, Madisonville
- Shoe Stores, Madisonville - Mens, Womens & Kids Shoes
- Shopping & Shopping Services, Madisonville
- Siding Contractors, Madisonville - Vinyl Siding, Wood, Metal & Aluminum Siding Contractors - Installation & Repair
- Signs, Madisonville
- Skin Care & Cosmetology Salons, Madisonville
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- Skin Care Products & Treatments, Madisonville
- Small Business & Office Equipment Repair Services, Madisonville
- Snacks & Desserts, Madisonville
- Social Security And Disability Attorneys & Lawyers, Madisonville
- Social Security And Disability Lawyers & Attorneys, Madisonville
- Social Security Counselors & Representatives, Madisonville
- Social Service Organizations Volunteer Services, Madisonville
- Social Services & Welfare, Madisonville
- Social Workers & Services, Madisonville
- Societies & Foundation Associations, Madisonville
- Sod & Sodding Service, Madisonville
- Southern Style Restaurants, Madisonville
- Special Events & Party Supply Rental, Madisonville
- Special Interest Schools Or Instruction, Madisonville
- Special Needs Transportation, Madisonville
- Specialty Animal Services, Madisonville
- Specialty Stores, Madisonville
- Sporting Goods Stores, Madisonville
- Sports Bars & Lounges, Madisonville
- Sprinkler System Contractors, Madisonville - Garden & Lawn Sprinkler System Installation & Repair
- Staffing & Support Services, Madisonville
- State Government, Madisonville
- Stationery & Office Supplies, Madisonville
- Steak House Restaurants, Madisonville
- Steel & Metal Goods, Madisonville - Steel Distributors
- Steel Manufacturers, Madisonville
- Stock & Bond Brokers & Dealers, Madisonville
- Stocks & Bond Brokers, Madisonville
- Storage Trailers & Containers, Madisonville
- Substance Abuse Clinics, Madisonville - Alcoholism, Addiction & Drug Abuse Treatment Centers
- Substance Abuse Services, Madisonville
- Surplus & Salvage Merchandise, Madisonville
- Surveyor Services, Madisonville - Surveying Service
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